{"id":179,"date":"2020-01-09T06:09:06","date_gmt":"2020-01-09T06:09:06","guid":{"rendered":"http:\/\/inksfortoys.com\/blog\/?p=179"},"modified":"2020-10-21T16:42:33","modified_gmt":"2020-10-21T16:42:33","slug":"en-71-organic-chemical-compounds","status":"publish","type":"post","link":"https:\/\/inksfortoys.com\/blog\/en-71-organic-chemical-compounds\/","title":{"rendered":"EN 71- Organic Chemical Compounds"},"content":{"rendered":"\n

Table lists the range of materials and their intended use as toys along with the chemicals that have been used on these materials. <\/p>\n\n\n\n

CHEMICAL
MATERIAL<\/td>		TYPES
OF
TOYS<\/td>		FLAME
RETARDANTS<\/td>		COLORANTS<\/td>PRIMARY
AROMATIC
AMINES<\/td>		MONOMERS<\/td>SOLVENTS
MIGRATIONS<\/td>		SOLVENT
INHALATIONS<\/td>		WOOD
PRESERVATIVES<\/td>		PRESER-
VATIVES<\/td>		PLASTICIZES<\/td><\/tr>
POLYMER<\/td>Toys intended to be mouthed by children under 3 years of age; <\/td><\/td><\/td><\/td> \u2714 <\/td> \u2714 <\/td><\/td><\/td><\/td> \u2714 <\/td><\/tr>
POLYMER<\/td>Toys, or their accessible components, with a mass of 150g or less intended to be played with in the hands by children under 3 years of age <\/td><\/td><\/td><\/td> \u2714 <\/td> \u2714 <\/td><\/td><\/td><\/td> \u2714 <\/td><\/tr>
WOOD<\/td> “<\/td><\/td>\u2714 <\/td> \u2714 <\/td><\/td><\/td><\/td> \u2714 <\/td><\/td><\/td><\/tr>
PAPER<\/td> “<\/td><\/td> \u2714 <\/td> \u2714 <\/td><\/td><\/td><\/td><\/td><\/td><\/td><\/tr>
TEXTILE<\/td>Toys or their accessible components intended for children under 3 years of age <\/td> \u2714 <\/td> \u2714 <\/td> \u2714 <\/td><\/td><\/td><\/td><\/td><\/td><\/td><\/tr>
LEATHER<\/td> “<\/td><\/td> \u2714 <\/td> \u2714 <\/td><\/td><\/td><\/td><\/td> \u2714 <\/td><\/td><\/tr>
POLYMER<\/td>Mouthpiece components of mouth actuated toys <\/td><\/td><\/td><\/td> \u2714 <\/td> \u2714 <\/td><\/td><\/td><\/td> \u2714 <\/td><\/tr>
WOOD <\/td> “<\/td><\/td> \u2714 <\/td> \u2714 <\/td><\/td><\/td><\/td> \u2714 <\/td><\/td><\/td><\/tr>
PAPER<\/td> “<\/td><\/td> \u2714 <\/td> \u2714 <\/td><\/td><\/td><\/td><\/td><\/td><\/td><\/tr>
POLYMER<\/td>Inflatable toys with a surface greater than 0.5m2 when fully inflated <\/td><\/td><\/td><\/td><\/td><\/td> \u2714 <\/td><\/td><\/td><\/td><\/tr>
POLYMER<\/td>Toys worn over the mouth or nose <\/td><\/td><\/td><\/td> \u2714 <\/td><\/td> \u2714 <\/td><\/td><\/td><\/td><\/tr>
TEXTILE<\/td> “<\/td><\/td> \u2714 <\/td> \u2714 <\/td><\/td><\/td> \u2714 <\/td><\/td><\/td><\/td><\/tr>
PAPER <\/td> ” <\/td><\/td> \u2714 <\/td> \u2714 <\/td><\/td><\/td><\/td><\/td><\/td><\/td><\/tr>
POLYMER<\/td>Toys which the child can enter <\/td><\/td><\/td><\/td><\/td><\/td> \u2714 <\/td><\/td><\/td><\/td><\/tr>
TEXTILE<\/td> “<\/td><\/td><\/td><\/td><\/td><\/td> \u2714 <\/td><\/td><\/td><\/td><\/tr>
POLYMER<\/td>Components of graphic instruments sold as toys or used in toys <\/td><\/td><\/td><\/td> \u2714 <\/td> \u2714 <\/td><\/td><\/td><\/td><\/td><\/tr>
WOOD<\/td>Wooden toys (and their accessible components) for indoor use <\/td><\/td><\/td><\/td><\/td><\/td><\/td> \u2714 <\/td><\/td><\/td><\/tr>
WOOD<\/td>Wooden toys (and their accessible components) for outdoor use <\/td><\/td><\/td><\/td><\/td><\/td><\/td> \u2714 <\/td><\/td><\/td><\/tr>
POLYMER<\/td>Toys and components of toys which mimic food <\/td><\/td><\/td><\/td> \u2714 <\/td> \u2714 <\/td><\/td><\/td><\/td> \u2714 <\/td><\/tr>
ALL<\/td>Solid toy materials intended to leave a trace <\/td><\/td> \u2714 <\/td> \u2714 <\/td><\/td><\/td><\/td><\/td><\/td><\/td><\/tr>
LIQUID<\/td>Coloured accessible liquids in toys <\/td><\/td> \u2714 <\/td> \u2714 <\/td><\/td><\/td><\/td><\/td> \u2714 <\/td><\/td><\/tr>
LIQUID<\/td>Non -coloured accessible liquids in toys <\/td><\/td><\/td><\/td><\/td><\/td><\/td><\/td> \u2714 <\/td><\/td><\/tr>
ALL<\/td>Modelling clay, play clay and similar, except those chemical toys addressed by EN71 – 5 <\/td><\/td> \u2714 <\/td> \u2714 <\/td><\/td><\/td><\/td><\/td> \u2714 <\/td><\/td><\/tr>
ALL<\/td>Balloon -making compounds <\/td><\/td> \u2714 <\/td> \u2714 <\/td><\/td><\/td> \u2714 <\/td><\/td><\/td><\/td><\/tr>
ALL<\/td>Imitation tattoos with adhesive <\/td><\/td> \u2714 <\/td> \u2714 <\/td><\/td> \u2714 <\/td><\/td><\/td> \u2714 <\/td><\/td><\/tr>
POLYMER<\/td>Imitation jewelry <\/td><\/td><\/td><\/td> \u2714 <\/td> \u2714 <\/td><\/td><\/td><\/td> \u2714 <\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n

Following are the chemicals and their action limits: <\/h2>\n\n\n\n

\u2714 5- Monomers :-<\/strong><\/p>\n\n\n\n

EN-71 sets limits on certain monomers, which release- <\/p>\n\n\n\n

  • Acryl amide: 0.02mg\/l <\/li>
  • Bisphenol A: 0.1mg\/l <\/li>
  • Formaldehyde: 2.5mg\/l <\/li>
  • Phenol: 15mg\/l <\/li>
  • Styrene: 0.75 mg\/l <\/li><\/ul>\n\n\n\n

    \u2714 10- Solvents Inhalation :-<\/strong><\/p>\n\n\n\n

    These solvents, which raise the risk of inhalation, are: <\/p>\n\n\n\n

    • Toluene: used for softening plastic, 260 microgram\/m3 <\/li>
    • Ethylbenzene: present as residues in coating, 5000 microgram\/m3 <\/li>
    • Xylenes: sometimes present in PVC, residue in (phthalate) plasticisers, 870 microgram\/m3 <\/li>
    • Mesitylene: presence is found in PVC & acrylic resins, 2500 microgram\/m3 <\/li>
    • Trichloroethylene: occurs in PVC & elastomers, 33 microgram\/m3<\/li>
    • Dichloromethane:it is a blowing agent for PU foams & is present in adhesive systems, 3000 micrpgram\/m3 <\/li>
    • N-Hexane: solvent in rubber cements, 1800 micrpgram\/m3 <\/li>
    • Nitrobenzene: toxic pungent solvent & sometimes present in EVA, 33 microgram\/m3 <\/li>
    • Cyclohexanone: a pungent solvent, most of the times found in coatings which have not been fully aired after application, especially those used on PVC inflatable toys, 136 microgram\/m3 <\/li>
    • 3,5,5-Trimethyl-2-cyclohexene-1-one (isophorone): a solvent with a low-odour threshold that has been released from coatings used on PVC inflatable toys, 200 microgram\/m3. <\/li><\/ul>\n\n\n\n

      \u2714 4-Plasticizers:-<\/strong> Action limits 0.03mg\/l <\/p>\n\n\n\n

      • Triphenyl phosphate <\/li>
      • Tri-o-cresyl phosphate <\/li>
      • Tri-m-cresyl phosphate<\/li>
      • Tri-p-cresyl phosphate <\/li><\/ul>\n\n\n\n

        \u2714 2-Flame retardants<\/strong>:-<\/p>\n\n\n\n

        • Tri-o-cresyl phosphate (78-30-8): 50mg\/kg <\/li>
        • Tris (2-chloroethyl) phosphate (115-96-8): 5mg\/kg <\/li><\/ul>\n\n\n\n

          \u2714 16-colorants:- <\/strong>Action Limit 10mg\/kg \uf0b7 Acid Red 26 (3761\u201353\u20133) <\/p>\n\n\n\n

          • Acid Violet 49 (1694\u201309\u20133)<\/li>
          • Basic Red 9 (569\u201361\u20139) <\/li>
          • Basic Violet 1 (8004\u201387\u20133) <\/li>
          • Basic Violet 3 (548\u201362\u20139) <\/li>
          • Disperse Blue 1 (2475\u201345\u20138) <\/li>
          • Disperse Blue 3 (2475\u201346\u20139) <\/li>
          • Blue 106 (12223\u201301\u20137) <\/li>
          • Disperse Blue 124 (61951\u201351\u20137) <\/li>
          • Disperse Yellow 3 (2832\u201340\u20138) <\/li>
          • Orange 3 (730\u201340\u20135) <\/li>
          • Disperse Orange 37\/76 (12223\u201333\u20135, 13301\u2013 61\u20136) <\/li>
          • Disperse Red 1 (2872\u201352\u20138) <\/li>
          • Solvent Yellow 1 (60\u201309\u20133) <\/li>
          • Solvent Yellow 2 (60\u201311\u20137) <\/li>
          • Solvent Yellow 3 (97\u201356\u20133) <\/li><\/ul>\n\n\n\n

            \u2714 9- Primary aromatic amines:- <\/strong>Action limit 5mg\/kg <\/p>\n\n\n\n

            • Benzidine (92\u201387\u20135) <\/li>
            • 2-Naphthylamine (91\u201359\u20138) <\/li>
            • 4-Chloroaniline (106\u201347\u20138) <\/li>
            • 3.3′-Dichlorobenzidine (91\u201394\u20131) <\/li>
            • 3,3′-Dimethoxybenzidine (119\u201390\u20134) <\/li>
            • 3.3′-Dimethylbenzidine (119\u201393\u20137) <\/li>
            • o-Toluidine (95\u201353\u20134) <\/li>
            • 2-Methoxyaniline (o-Anisidine) (90\u201304\u20130) <\/li>
            • Aniline 62\u201353\u20133 <\/li><\/ul>\n\n\n\n

              \u2714 14-Solvents migration<\/strong> :-<\/strong><\/p>\n\n\n\n

              • Trichloroethylene (79\u201301\u20136): 0.02mg\/l <\/li>
              • Dichloromethane (75\u201309\u20132): 0,06 mg\/l <\/li>
              • 2-Methoxyethyl acetate (110\u201349\u20136): 0.5 mg\/l <\/li>
              • 2-Ethoxyethanol (110\u201380\u20135): 0.5 mg\/l <\/li>
              • 2-Ethoxyethyl acetate (111\u201315\u20139): 0.5 mg\/l <\/li>
              • Bis(2-methoxyethyl) ether (111\u201396\u20136): 0.5 mg\/l <\/li>
              • 2-Methoxypropyl acetate (70657\u201370\u20134): 0.5 mg\/l <\/li>
              • Methanol (67\u201356\u20131): 5 mg\/l <\/li>
              • Nitrobenzene (98\u201395\u20133): 0.02mg\/l <\/li>
              • Cyclohexanone (108\u201394\u20131): 46 mg\/l <\/li>
              • 3,5,5-Trimethyl-2-cyclohexene-1-one (78\u201359\u20131): 3 mg\/l <\/li>
              • Toluene (108\u201388\u20133): 2 mg\/l <\/li>
              • Ethylbenzene (100\u201341\u20134): 1 mg\/l <\/li>
              • Xylene (all isomers): 2 mg\/l (total) <\/li><\/ul>\n\n\n\n

                <\/p>\n","protected":false},"excerpt":{"rendered":"

                Table lists the range of materials and their intended use as toys along with the […]<\/p>\n","protected":false},"author":2,"featured_media":212,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[4,3,5,6],"tags":[],"class_list":["post-179","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-pad-printing","category-r-d","category-screen-printing","category-spray-coating"],"yoast_head":"\nEN 71- Organic Chemical Compounds - inks for toys<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"http:\/\/inksfortoys.com\/blog\/en-71-organic-chemical-compounds\/\" \/>\n<meta property=\"og:locale\" content=\"en_US\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"EN 71- Organic Chemical Compounds - inks for toys\" \/>\n<meta property=\"og:description\" content=\"Table lists the range of materials and their intended use as toys along with the […]\" \/>\n<meta property=\"og:url\" content=\"http:\/\/inksfortoys.com\/blog\/en-71-organic-chemical-compounds\/\" \/>\n<meta property=\"og:site_name\" content=\"inks for toys\" \/>\n<meta property=\"article:published_time\" content=\"2020-01-09T06:09:06+00:00\" \/>\n<meta property=\"article:modified_time\" content=\"2020-10-21T16:42:33+00:00\" \/>\n<meta property=\"og:image\" content=\"http:\/\/inksfortoys.com\/blog\/wp-content\/uploads\/2020\/01\/new-year-4728127_1920.jpg\" \/>\n\t<meta property=\"og:image:width\" content=\"1920\" \/>\n\t<meta property=\"og:image:height\" content=\"1117\" \/>\n\t<meta property=\"og:image:type\" content=\"image\/jpeg\" \/>\n<meta name=\"author\" content=\"ocean kumar\" \/>\n<meta name=\"twitter:card\" content=\"summary_large_image\" \/>\n<meta name=\"twitter:label1\" content=\"Written by\" \/>\n\t<meta name=\"twitter:data1\" content=\"ocean kumar\" \/>\n\t<meta name=\"twitter:label2\" content=\"Est. reading time\" \/>\n\t<meta name=\"twitter:data2\" content=\"3 minutes\" \/>\n<script type=\"application\/ld+json\" class=\"yoast-schema-graph\">{\"@context\":\"https:\/\/schema.org\",\"@graph\":[{\"@type\":\"Article\",\"@id\":\"http:\/\/inksfortoys.com\/blog\/en-71-organic-chemical-compounds\/#article\",\"isPartOf\":{\"@id\":\"http:\/\/inksfortoys.com\/blog\/en-71-organic-chemical-compounds\/\"},\"author\":{\"name\":\"ocean kumar\",\"@id\":\"https:\/\/inksfortoys.com\/blog\/#\/schema\/person\/acb319b7774d6a9140c5c3c03763671d\"},\"headline\":\"EN 71- Organic Chemical Compounds\",\"datePublished\":\"2020-01-09T06:09:06+00:00\",\"dateModified\":\"2020-10-21T16:42:33+00:00\",\"mainEntityOfPage\":{\"@id\":\"http:\/\/inksfortoys.com\/blog\/en-71-organic-chemical-compounds\/\"},\"wordCount\":550,\"commentCount\":0,\"publisher\":{\"@id\":\"https:\/\/inksfortoys.com\/blog\/#organization\"},\"image\":{\"@id\":\"http:\/\/inksfortoys.com\/blog\/en-71-organic-chemical-compounds\/#primaryimage\"},\"thumbnailUrl\":\"https:\/\/inksfortoys.com\/blog\/wp-content\/uploads\/2020\/01\/new-year-4728127_1920.jpg\",\"articleSection\":[\"Pad Printing\",\"R & D\",\"Screen printing\",\"Spray coating\"],\"inLanguage\":\"en-US\",\"potentialAction\":[{\"@type\":\"CommentAction\",\"name\":\"Comment\",\"target\":[\"http:\/\/inksfortoys.com\/blog\/en-71-organic-chemical-compounds\/#respond\"]}]},{\"@type\":\"WebPage\",\"@id\":\"http:\/\/inksfortoys.com\/blog\/en-71-organic-chemical-compounds\/\",\"url\":\"http:\/\/inksfortoys.com\/blog\/en-71-organic-chemical-compounds\/\",\"name\":\"EN 71- Organic Chemical Compounds - 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